Aluminum Antimonide
SAFETY DATA SHEET
1 PRODUCT AND SUPPLIER IDENTIFICATION
Product Name: Aluminum Antimonide
Formula: AlSb
Supplier: ESPI Metals
1050 Benson Way
Ashland, OR 97520
Telephone: 800-638-2581
Fax: 541-488-8313
Email: This email address is being protected from spambots. You need JavaScript enabled to view it.
Emergency: Infotrac 800-535-5053 (US) or 352-323-3500 (24 hour)
Recommended Uses: Scientific Research
2 HAZARDS IDENTIFICATION
GHS Classification (29 CFR 1910.1200): Acute toxicity - oral, category 4, Acute toxicity - inhalation, category 4.
GHS Label Elements:
Signal Word: Warning
Hazard Statements: H302 Harmful if swallowed, H332 Harmful if inhaled.
Precautionary Statements: P261 Avoid breathing dust/fume/gas/mist/vapors/spray, P264 Wash hands thoroughly after handling, P270 Do not eat, drink or smoke when using this product, P271 Use only outdoors or in a well-ventilated area, P301+P304+P312 IF SWALLOWED OR INHALED: Call a POISON CENTER or doctor/physician IF you feel unwell, P330 Rinse mouth, P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing, P501 Dispose of contents/container in accordance with local, state or federal regulations.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient: Aluminum Antimonide
CAS#: 25152-52-7
%: 100
EC#: 246-667-3
4 FIRST AID MEASURES
General Measures: Remove patient from area of exposure.
INHALATION: Remove to fresh air, keep warm and quiet, give oxygen if breathing is difficult. Seek immediate medical attention.
INGESTION: Rinse mouth with water. Do not induce vomiting. Seek immediate medical attention. Never induce vomiting or give anything by mouth to an unconscious person.
SKIN: Remove contaminated clothing, brush material off skin, wash affected area with soap and water. Seek medical attention.
EYES: Flush eyes with lukewarm water, including under upper and lower eyelids, for at least 15 minutes. Seek medical attention.
Most Important Symptoms/Effects, Acute and Delayed: May cause irritation. See section 11 for more information.
Indication of Immediate Medical Attention and Special Treatment: No other information available.
5 FIREFIGHTING MEASURES
Extinguishing Media: Use suitable extinguishing agent for surrounding materials and type of fire.
Unsuitable Extinguishing Media: No information available.
Specific Hazards Arising from the Material: May emit toxic fumes under fire conditions.
Special Protective Equipment and Precautions for Firefighters: Full face, self-contained breathing apparatus and full protective clothing to prevent contact with skin and eyes.
6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: Wear appropriate respiratory and protective equipment specified in section 8. Isolate spill area and provide ventilation. Avoid breathing dust or fume. Avoid contact with skin and eyes. Eliminate all sources of ignition.
Methods and Materials for Containment and Cleaning Up: Avoid dust formation. Cleanup spills with a vacuum system utilizing a high efficiency particulate air (HEPA) filtration system and place in a properly labeled closed container for further handling and disposal.
Environmental Precautions: Do not allow to enter drains or to be released to the environment.
7 HANDLING AND STORAGE
Precautions for Safe Handling: Handle in an enclosed, controlled process. Avoid creating dust. Avoid breathing dust or fumes. Provide adequate ventilation if dusts are created. Avoid contact with skin and eyes. Wash thoroughly before eating or smoking. See section 8 for information on personal protection equipment.
Conditions for Safe Storage, Including Any Incompatibilities: Store in a cool, dry, well-ventilated area. Store material tightly sealed in properly labeled containers. See section 10 for more information on incompatible materials.
8 EXPOSURE CONTROLS AND PERSONAL PROTECTION
Exposure Limits: OSHA/PEL: ACGIH/TLV:
Aluminum Antimonide No exposure limit established No exposure limit established
Antimony and compounds (as Sb) 0.5 mg/m3 0.5 mg/m3
Appropriate Engineering Controls: Ensure adequate ventilation to maintain exposures below occupational limits. Whenever possible the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne dust and fume to meet established occupational exposure limits. Use good housekeeping and sanitation practices. Do not use tobacco or food in work area. Wash thoroughly before eating or smoking. Do not blow dust off clothing or skin with compressed air. Clothing worn in areas of exposure to arsenic dust or fume should be restricted to the workplace and laundered regularly.
Individual Protection Measures, Such as Personal Protective Equipment:
Respiratory Protection: Wear a NIOSH/MSHA approved respirator when high concentrations are present.
Eye Protection: Safety glasses.
Skin Protection: Wear impermeable gloves, protective work clothing as necessary.
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Form: Powder
Color: No data
Odor: Not determined
Odor Threshold: Not determined
pH: N/A
Melting Point: No data
Boiling Point: No data
Flash Point: N/A
Evaporation Rate: N/A
Flammability: No data
Upper Flammable Limit: No data
Lower Flammable Limit: No data
Vapor Pressure: No data
Vapor Density: N/A
Relative Density (Specific Gravity): No data
Solubility in H2O: Insoluble
Partition Coefficient (n-octanol/water): Not determined
Autoignition Temperature: No data
Decomposition Temperature: No data
Viscosity: N/A
10 STABILITY AND REACTIVITY
Reactivity: No specific test data available.
Chemical Stability: Stable under recommended storage conditions.
Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
Conditions to Avoid: No data
Incompatible Materials: Strong acids, oxidizing agents.
Hazardous Decomposition Products: Aluminum oxides, antimony oxides.
11 TOXICOLOGICAL INFORMATION
Likely Routes of Exposure: Inhalation, skin and eyes
Symptoms of Exposure: May cause irritation to eyes and abraded skin. May cause irritation to lungs.
Acute and Chronic Effects:
Aluminum: There is strong evidence that aluminum (compounds) can cause irritation following exposure via either inhalation or injection. Modest evidence of an effect exists for reproductive toxicity following oral exposure, for neurological toxicity following either oral or injection exposure, and for bone toxicity following injection exposure. All other effects were judged to be supported by either limited evidence or no clear evidence at all.1
Antimony: Antimony and its compounds are irritating to the skin and mucous membranes and are systemic poisons. Effects are reported to include a metallic taste in the mouth, vomiting, colic, loss of appetite and weight, and diarrhea. In addition, dermatitis may result which starts as an inflammation of the hair follicles and can progress through pus formation and sloughing to leave a contracted scar. Chronic antimony exposure cause alterations of the ECG, laryngitis, bronchitis, pneumonitis, pneumoconiosis, and ulceration of the nasal septum and larynx.
Acute Toxicity: No data
Carcinogenicity: NTP: Not identified as carcinogenic IARC: Not identified as carcinogenic
To the best of our knowledge the chemical, physical and toxicological characteristics of the substance are not fully known.
12 ECOLOGICAL INFORMATION
Ecotoxicity: No data
Persistence and Degradability: No data
Bioaccumulative Potential: No data
Mobility in Soil: No data
Other Adverse Effects: Danger to drinking water and to aquatic organisms. Do not allow material to be released to the environment. No further relevant information available.
13 DISPOSAL CONSIDERATIONS
Waste Disposal Method:
Product: Dispose of in accordance with Federal, State and Local regulations.
Packaging: Dispose of in accordance with Federal, State and Local regulations.
14 TRANSPORT INFORMATION
UN Number: UN1549
UN Proper Shipping Name: Antimony compounds, inorganic, solid, n.o.s. (Aluminum Antimonide)
Transport Hazard Class: 6.1
Packing Group: III
Marine Pollutant: No
15 REGULATORY INFORMATION
TSCA Listed: Yes
DSL Listed: No
Regulation (EC) No 1272/2008 (CLP): Acute toxicity - oral, category 4, Acute toxicity - inhalation, category 4.
WHMIS 2015 Classification (CPR, SOR/88-66): Acute toxicity.
HMIS Ratings: Health: 2 Flammability: 0 Physical: 0
NFPA Ratings: Health: 2 Flammability: 0 Instability: 0
Chemical Safety Assessment: A chemical safety assessment has not been carried out.
16 OTHER INFORMATION
1Krewski et al. (2007) Human Health Risk Assessment for Aluminum, Aluminum Oxide, and Aluminum Hydroxide, http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2782734/
The information contained in this document is based on the state of our knowledge at the time of publication and is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide. ESPI Metals makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. ESPI Metals shall not be held liable for any damages resulting from handling or from contact with the above product. Users should satisfy themselves that they have all current data relevant to their particular use.
Prepared by: ESPI Metals
Revised/Reviewed: May 2015
TSCA Listed: Yes
DOT Regulations:
Hazard Class: 6.1
Identification Number: UN1557
Packing Group: II
Proper Shipping Name: Arsenic compound, solid, n.o.s., (Aluminum Arsenide)